Ah, they just opened up the ability to connect devices to an account. I have it on my tablet and phone simultaneously. The tablet only fetches messages when I open the app though. Not sure if that's intended, or something about my device, and I actually prefer it to notifications on both anyway; which other messagers do on the same devices.
I'm not sure how it would work on separate profiles on the same device though. If it's one account, it would seem strange if it did work fully since they're both linked to the same number/account. Two accounts might work, I dunno