this post was submitted on 27 Dec 2023
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A new crash recently in Alabama, but a reminder to something that we all know. Burning Teslas are far more difficult to extinguish than any other car.

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[–] GetriFriedRisa@startrek.website 5 points 11 months ago* (last edited 11 months ago) (1 children)

There's plenty of proof in academic literature. FePO4 is quite stable because of the quirks in iron's valance up to about 500C. But the combination of of lithium skews the valance effects at high temperatures to start losing oxygen at 250C.

Please review the following literature for more information:

  1. C. Delacourt, P. Poizot, J-.M. Tarascon, and C. Masquelier, Nat Mater., 4, 254 (2005).
  2. J.L Dodd, R. Yazami, and B. Fultz, Electrochem. Solid-State Let., 9, A151 (2006).
  3. G. Chen, .XSong, and T. J. Richardson, J. Electrochem. Soc,. 154, 4627 (2007).
[–] Nomecks@lemmy.ca -2 points 11 months ago (1 children)

How much oxygen are we talking here? I'm guessing not much, as they wouldn't be allowed to sell lifepo4 batteries as non combustible if they had any real chance of causing a self sustaining fire. So level with me so I don't have to trudge through a bunch of academic papers: How much oxygen do they mention?

[–] GetriFriedRisa@startrek.website 4 points 11 months ago

The stoichometry comes out with 2:1 moles of lfp to diatomic oxygen which is significant

The combustibility you're referring to is a legal definition not a scientific one