If I had to do encrypted btrfs RAID from scratch, I would probably:
- Set up LUKS on both discs
- Unlock both
- Create a btrfs partition on one mapper
- Add the other with
btfs device add /path/to/mapper /path/to/btrfs/part
- Balance with
btrfs balance start -mconvert=raid1 -dconvert=raid1 /path/to/btrfs/part
- Add LUKS' to crypttab, btrfs partition to fstab and rebuild/configure bootloader as necessary
In that scenario, you would probably want to use a keyfile to unlock the other disc without rentering some password.
Now, that's from the top of my head and seems kinda stupidly complicated to me. iirc btrfs has a stable feature to convert ext4 to btrfs. It shouldn't matter whatever happens outside, so you could take your chances and just try that on your ext volume
(Edit: But to be absolutely clear: I would perform a backup first :D)