Sure. Almost 40 years ago I started learning to program as a kid, and the only reason I knew the word "syntax" at all was because the default error message in my computer's BASIC interpreter was "SYNTAX ERROR". I didn't learn what it actually meant until many years later, in English class.
I taught myself with the excellent Usborne books, which are now all downloadable for free from their website. You won't be able to use them as-is (unless you get your kids to use an emulator for an old 8-bit home computer), but I'm sure you can still get some useful ideas, and maybe even copy small sections here and there.
As others have mentioned, my school also taught us a little LOGO, which was a bit of fun for me but rather simple. I remember that most of my classmates enjoyed it, though.
PS2 can only run PS1 games (close to) natively from optical discs. The system that switches the PS2 over to PS1 mode can only be triggered physically by the drive, and once in PS1 mode the console can no longer access most of the PS2 hardware, including any storage attached to the network adapter.
There is a way to "convert" PS1 games to run from internal storage (POPStation), but it actually just wraps the PS1 image in a software emulator for PS2.